Organometallic Ion Chemistry

Paperback Engels 2014 9789401065368
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Samenvatting

Organometallic Ion Chemistry features eight chapters, written by acknowledged authorities, covering the gas-phase chemistry of organometallic ions. Topics covered include: periodic trends in gas-phase thermochemistry of transition metal-ligand systems; ab initio calculations to determine electronic structure, geometric structure, and thermochemistry of metal-containing systems; electronic state effects on metal ion reactivity; organometallic ion photochemistry; applications of gas-phase electron transfer equilibria in organometallic redox thermochemistry. Also included are state of the art mass spectrometric instrumentation used in such studies. Finally, the book features - for the first time in one place - a comprehensive list (containing over 1500 entries) of metal ion-ligand bond energies, obtained from theory and experiment.
An invaluable reference source for ion chemists, organometallic chemists and surface chemists, at both expert and graduate student levels.

Specificaties

ISBN13:9789401065368
Taal:Engels
Bindwijze:paperback
Aantal pagina's:337
Uitgever:Springer Netherlands

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Inhoudsopgave

Preface. 1. Gas-Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends; P.B. Armentrout, B.L. Kickel. 2. Ab initio Calculations Applied to Problems in Metal Ion Chemistry; C.W. Bauschlicher Jr., S.R. Langhoff, H. Partridge. 3. The Electronic Structure of the Neutral, Mono and Di Positive Transition Metal Nitrides, ScN, TiN, VN, and CrN; J.F. Harrison, K. La Kunze. 4. Fundamental Studies of Functionalized Hydrocarbons with Transition Metal Ions; K. Eller. 5. Electronic State Effects in Sigma Bond Activation by First Row Transition Metal Ions: the Ion Chromatography Technique; P.A.M. Van Koppen, P.R. Kemper, M.T. Bowers. 6. Development of a Fourier Transform Ion Cyclotron Resonance (FTICR) Mass Spectrometry Method for Studies of Metal Ion Excited States; D.H. Russell, J.V.B. Oriedo, T. Solouki. 7. Gas Phase Organometallic Ion Photochemistry; I.B. Surjasasmita, Y.A. Ranasinghe, B.S. Freiser. 8. Applications of Gas-Phase Electron-Transfer Equilibria in Organometallic Redox Thermochemistry; D.E. Richardson. Table of Bond Energies.

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        Organometallic Ion Chemistry